Paper 1, Section II, B

Principles of Quantum Mechanics | Part II, 2021

(a) A group GG of transformations acts on a quantum system. Briefly explain why the Born rule implies that these transformations may be represented by operators U(g):H→HU(g): \mathcal{H} \rightarrow \mathcal{H} obeying

U(g)†U(g)=1HU(g1)U(g2)=eiϕ(g1,g2)U(g1⋅g2)\begin{aligned} U(g)^{\dagger} U(g) &=1_{\mathcal{H}} \\ U\left(g_{1}\right) U\left(g_{2}\right) &=e^{i \phi\left(g_{1}, g_{2}\right)} U\left(g_{1} \cdot g_{2}\right) \end{aligned}

for all g1,g2∈Gg_{1}, g_{2} \in G, where ϕ(g1,g2)∈R\phi\left(g_{1}, g_{2}\right) \in \mathbb{R}.

What additional property does U(g)U(g) have when GG is a group of symmetries of the Hamiltonian? Show that symmetries correspond to conserved quantities.

(b) The Coulomb Hamiltonian describing the gross structure of the hydrogen atom is invariant under time reversal, t↦−tt \mapsto-t. Suppose we try to represent time reversal by a unitary operator TT obeying U(t)T=TU(−t)U(t) T=T U(-t), where U(t)U(t) is the time-evolution operator. Show that this would imply that hydrogen has no stable ground state.

An operator A:H→HA: \mathcal{H} \rightarrow \mathcal{H} is antilinear if

A(a∣α⟩+b∣β⟩)=aˉA∣α⟩+bˉA∣β⟩A(a|\alpha\rangle+b|\beta\rangle)=\bar{a} A|\alpha\rangle+\bar{b} A|\beta\rangle

for all ∣α⟩,∣β⟩∈H|\alpha\rangle,|\beta\rangle \in \mathcal{H} and all a,b∈Ca, b \in \mathbb{C}, and antiunitary if, in addition,

⟨β′∣α′⟩=⟨β∣α⟩‾,\left\langle\beta^{\prime} \mid \alpha^{\prime}\right\rangle=\overline{\langle\beta \mid \alpha\rangle},

where ∣α′⟩=A∣α⟩\left|\alpha^{\prime}\right\rangle=A|\alpha\rangle and ∣β′⟩=A∣β⟩\left|\beta^{\prime}\right\rangle=A|\beta\rangle. Show that if time reversal is instead represented by an antiunitary operator then the above instability of hydrogen is avoided.

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