A4.18

Statistical Physics and Cosmology | Part II, 2002

What is an ideal gas? Explain how the microstates of an ideal gas of indistinguishable particles can be labelled by a set of integers. What range of values do these integers take for (a) a boson gas and (b) a Fermi gas?

Let EiE_{i} be the energy of the ii-th one-particle energy eigenstate of an ideal gas in thermal equilibrium at temperature TT and let pi(ni)p_{i}\left(n_{i}\right) be the probability that there are nin_{i} particles of the gas in this state. Given that

pi(ni)=eβEini/Zi(β=1kT)p_{i}\left(n_{i}\right)=e^{-\beta E_{i} n_{i}} / Z_{i} \quad\left(\beta=\frac{1}{k T}\right)

determine the normalization factor ZiZ_{i} for (a) a boson gas and (b) a Fermi gas. Hence obtain an expression for nˉi\bar{n}_{i}, the average number of particles in the ii-th one-particle energy eigenstate for both cases (a) and (b).

In the case of a Fermi gas, write down (without proof) the generalization of your formula for nˉi\bar{n}_{i} to a gas at non-zero chemical potential μ\mu. Show how it leads to the concept of a Fermi energy ϵF\epsilon_{F} for a gas at zero temperature. How is ϵF\epsilon_{F} related to the Fermi momentum pFp_{F} for (a) a non-relativistic gas and (b) an ultra-relativistic gas?

In an approximation in which the discrete set of energies EiE_{i} is replaced with a continuous set with momentum pp, the density of one-particle states with momentum in the range pp to p+dpp+d p is g(p)dpg(p) d p. Explain briefly why

g(p)p2Vg(p) \propto p^{2} V

where VV is the volume of the gas. Using this formula, obtain an expression for the total energy EE of an ultra-relativistic gas at zero chemical potential as an integral over pp. Hence show that

EVTα,\frac{E}{V} \propto T^{\alpha},

where α\alpha is a number that you should compute. Why does this result apply to a photon gas?

Using the formula ()(*) for a non-relativistic Fermi gas at zero temperature, obtain an expression for the particle number density nn in terms of the Fermi momentum and provide a physical interpretation of this formula in terms of the typical de Broglie wavelength. Obtain an analogous formula for the (internal) energy density and hence show that the pressure PP behaves as

PnγP \propto n^{\gamma}

where γ\gamma is a number that you should compute. [You need not prove any relation between the pressure and the energy density you use.] What is the origin of this pressure given that T=0T=0 by assumption? Explain briefly and qualitatively how it is relevant to the stability of white dwarf stars.

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