Paper 2, Section II, D

Quantum Mechanics | Part IB, 2010

A particle of mass mm moves in a one-dimensional potential defined by

V(x)={∞ for x<00 for 0⩽x⩽aV0 for a<xV(x)= \begin{cases}\infty & \text { for } x<0 \\ 0 & \text { for } 0 \leqslant x \leqslant a \\ V_{0} & \text { for } a<x\end{cases}

where aa and V0V_{0} are positive constants. Defining c=[2m(V0−E)]1/2/ℏc=\left[2 m\left(V_{0}-E\right)\right]^{1 / 2} / \hbar and k=k= (2mE)1/2/ℏ(2 m E)^{1 / 2} / \hbar, show that for any allowed positive value EE of the energy with E<V0E<V_{0} then

c+kcot⁡ka=0c+k \cot k a=0

Find the minimum value of V0V_{0} for this equation to have a solution.

Find the normalized wave function for the particle. Write down an expression for the expectation value of xx in terms of two integrals, which you need not evaluate. Given that

⟨x⟩=12k(ka−tan⁡ka),\langle x\rangle=\frac{1}{2 k}(k a-\tan k a),

discuss briefly the possibility of ⟨x⟩\langle x\rangle being greater than aa. [Hint: consider the graph of - ka cot kak a against ka.]k a .]

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